Synthesis and X-ray powder structures of three novel titanium phosphate compounds

Journal Article · Fri Aug 01 04:00:00 EDT 1997 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1006/jssc.1997.7470· OSTI ID:567616

Poojary, D M; Bortun, A I; Bortun, L N; Clearfield, A ^[1]

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1. Texas A&M Univ., College Station, TX (United States)

Three titanium phosphate porous compounds were prepared hydrothermally and their structures solved from their X-ray powder diffraction patterns collected on a laboratory X-ray source. The compound, [Ti{sub 3}(PO{sub 4}){sub 4}(H{sub 2}O){sub 2}] {center_dot} NH{sub 3} (1), crystallizes in triclinic symmetry with a = 8.2506(4), b = 8.7879(4), c = 5.1022(2) {angstrom}; {alpha} = 90.703(1), {beta} = 91.083(1), {gamma} = 110.158(1){degrees}; space group P{bar 1}, and Z = 1. The structure was solved ab initio by direct methods and refined by Rietveld methods.

• OSTI ID: 567616
• Journal Information: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 1 Vol. 132; ISSN 0022-4596; ISSN JSSCBI
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
66 PHYSICS
AMMONIA
CRYSTAL STRUCTURE
NMR SPECTRA
PHOSPHORUS 31
PHYSICAL PROPERTIES
SYMMETRY
TITANIUM PHOSPHATES