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Occurrence of organotins in municipal wastewater and sewage sludge and behavior in a treatment plant

Journal Article · · Environmental Science and Technology; (USA)
DOI:https://doi.org/10.1021/es00015a017· OSTI ID:5673099
 [1];  [2]
  1. Swiss Federal Institute for Water Resources and Water Pollution Control, Kastanienbaum (Switzerland)
  2. Swiss Federal Research Station, Waedenswil (Switzerland)
THe behavior of selected organotin species in a wastewater treatment plant of Zurich, Switzerland, was studied. In untreated wastewater, monobutyltin (MBT), dibutyltin (DBT), and tributyltin (TBT) were detected in the range of 136-564, 127-1,026, and 64-217 ng/L, respectively, of which 81-92% were associated with suspended solids. During treatment, the fraction of organotins in the particulate phase decreased with decreasing suspended solids concentration. All organotin species monitored were found to be efficiently removed from wastewater, mainly by sedimentation in the primary clarifier. In the secondary effluent, levels of different organotins were in the range of 7-47 ng/L. These compounds were transferred into sewage sludge, indicating that the most important process for the elimination of organotins was adsorption into sludge. Residues of MBT, DBT, and TBT in digested sludges were in the range of 0.10-0.97, 0.41-1.24, and 0.28-1.51 mg/kg (dry weight), respectively.
OSTI ID:
5673099
Journal Information:
Environmental Science and Technology; (USA), Journal Name: Environmental Science and Technology; (USA) Vol. 25:3; ISSN ESTHA; ISSN 0013-936X
Country of Publication:
United States
Language:
English