Conformational analysis by photoelectron spectroscopy

Journal Article · Thu Nov 01 04:00:00 EST 1979 · Angew. Chem. Int. Ed. Engl.; (United States)

DOI:https://doi.org/10.1002/anie.197908261· OSTI ID:5667608

Klessinger, M ^[1]; Rademacher, P

---

1. Organisch-Chemisches Institut der Universitaet, Muenster, Germany

The conformation of organic molecules may be determined by means of photoelectron (PE) spectroscopy if there are orbital interactions present which depend on a dihedral angle. Straightforward application of the method requires that all ionization bands of interest can be assigned unambiguously and that inductive effects and secondary orbital interactions do not occur or can be accounted for appropriately. In many cases, this method complements conventional methods of conformational analysis. PE conformational analysis is particularly suited to compounds containing vicinal lone pairs of ..pi.. systems. 105 references, 10 figures, 2 tables.

• OSTI ID: 5667608
• Journal Information: Angew. Chem. Int. Ed. Engl.; (United States), Journal Name: Angew. Chem. Int. Ed. Engl.; (United States) Vol. 18:11; ISSN ACIEA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400104 -- Spectral Procedures-- (-1987)
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AROMATICS
ELECTRON SPECTROSCOPY
ELECTRONIC STRUCTURE
MATHEMATICAL MODELS
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
SPECTROSCOPY
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS