Interaction of sulphur and nitrogen compounds with aluminum chloride
Journal Article
·
· Pet. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:5658532
A study was made of the interaction of diethylsulphide, dipropyldisulphide, diphenylsulphide, butylthiophans, benzthiophen, dibenzothiophen, quinoline and indole with aluminium chloride within the temperature range of 21 to 1000/sup 0/. All hetero-atomic compounds studied in hydrocarbon media at a temperature lower than 71/sup 0/ from complexes with aluminum chloride. During the intersection of diphenylsulphide with aluminum chloride thianthrene, polyphenylsulphides and benzene are formed. It was established that butylthiophens undergo partial isomerization and indole undergoes trimerization by the action of aluminum chloride.
- Research Organization:
- V.V. Kyubyshev State Univ., Tomsk, USSR
- OSTI ID:
- 5658532
- Journal Information:
- Pet. Chem. USSR (Engl. Transl.); (United States), Journal Name: Pet. Chem. USSR (Engl. Transl.); (United States) Vol. 20:3; ISSN PECHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
02 PETROLEUM
020500 -- Petroleum-- Products & By-Products
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
AROMATICS
AZINES
AZOLES
BENZENE
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
INDOLES
INTERACTIONS
ISOMERIZATION
MEDIUM TEMPERATURE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PYRIDINES
PYRROLES
QUINOLINES
SYNTHESIS
VERY HIGH TEMPERATURE
020500 -- Petroleum-- Products & By-Products
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
AROMATICS
AZINES
AZOLES
BENZENE
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
INDOLES
INTERACTIONS
ISOMERIZATION
MEDIUM TEMPERATURE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PYRIDINES
PYRROLES
QUINOLINES
SYNTHESIS
VERY HIGH TEMPERATURE