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U.S. Department of Energy
Office of Scientific and Technical Information

Actinide partitioning from actual Idaho chemical processing plant acidic tank waste using centrifugal contactors

Conference ·
OSTI ID:565348

The TRUEX process is being evaluated at the Idaho Chemical Processing Plant (ICPP) for the separation of the actinides from acidic radioactive wastes stored at the ICPP. These efforts have culminated in a recent demonstration of the TRUEX process with actual tank waste. This demonstration was performed using 24 stages of 2-cm diameter centrifugal contactors installed in a shielded hot cell at the ICPP Remote Analytical Laboratory. An overall removal efficiency of 99.97% was obtained for the actinides. As a result, the activity of the actinides was reduced from 457 nCi/g in the feed to 0.12 nCi/g in the aqueous raffinate, which is well below the U.S. NRC Class A LLW requirement of 10 nCi/g for non-TRU waste. Iron was partially extracted by the TRUEX solvent, resulting in 23% of the Fe exiting in the strip product. Mercury was also extracted by the TRUEX solvent (76%) and stripped from the solvent in the 0.25 M Na{sub 2}CO{sub 3} wash section.

Research Organization:
Idaho National Engineering Lab., Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE Office of Environmental Restoration and Waste Management, Washington, DC (United States)
DOE Contract Number:
AC07-94ID13223
OSTI ID:
565348
Report Number(s):
INEL/CON--97-00705; CONF-971004--; ON: DE98050471
Country of Publication:
United States
Language:
English