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Characterization of ceramics and intermetallics fabricated by self-propagating high-temperature synthesis

Technical Report ·
OSTI ID:5651846
Three efforts aimed at investigating the process of self-propagating high temperature synthesis (SHS) for the fabrication of structural ceramics and intermetallics are summarized. Of special interest was the influence of processing variables such as exothermic dopants, gravity, and green state morphology in materials produced by SHS. In the first effort directed toward the fabrication of SiC, exothermic dopants of yttrium and zirconium were added to SiO2 or SiO2 + NiO plus carbon powder mix and processed by SHS. This approach was unsuccessful since it did not produce the desired product of crystalline SiC. In the second effort, the influence of gravity was investigated by examining Ni-Al microstructures which were produced by SHS combustion waves traveling with and opposite the gravity direction. Although final composition and total porosities of the combusted Ni-Al compounds were found to be gravity independent, larger pores were created in those specimens which were combusted opposite to the gravity force direction. Finally, it was found that green microstructure has a significant effect on the appearance of the combusted piece. Severe pressing laminations were observed to arrest the combustion front for TiC samples.
Research Organization:
National Aeronautics and Space Administration, Cleveland, OH (USA). Lewis Research Center
OSTI ID:
5651846
Report Number(s):
N-89-25285; NASA-TM--102004; E--4710; NAS--1.15:102004
Country of Publication:
United States
Language:
English