Evaluation of porous carbon and ceramic supports for hyperfiltration
Porous carbon and ceramic tubes were evaluated as supports for dynamically formed zirconium (IV) hydrous oxide-polycarboxylic acid hyperfiltration membranes. The most promising membranes were formed on Union Carbide 6-C carbon tubes using a 150,000 molecular weight polyacrylic acid. Sodium chloride rejections as high as 97% were obtained at water fluxes of 80 gpd/ft{sup 2} compared with rejections of 90 to 95% and fluxes of 130 gpd/ft{sup 2} using the porous stainless steel-Acropor/Millipore supports. The effects of pressure, circulation velocity, and temperature on membrane flux and sodium chloride and Coalinga water rejections were studied. A small industrial module containing 6-C carbon supports with a 3.04 ft{sup 2} filtration surface gave a salt rejection of 86% and a product water flux of 60 gpd/ft{sup 2}.
- Research Organization:
- Massachusetts Inst. of Tech., Oak Ridge, TN (United States). School of Chemical Engineering Practice-Oak Ridge Station
- Sponsoring Organization:
- DOE; USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC05-84OR21400
- OSTI ID:
- 5641552
- Report Number(s):
- ORNL-MIT-124; ON: DE92013030
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
54 ENVIRONMENTAL SCIENCES
540220* -- Environment
Terrestrial-- Chemicals Monitoring & Transport-- (1990-)
CARBON
CARBOXYLIC ACIDS
CHALCOGENIDES
ELEMENTS
EVALUATION
FILTRATION
HYDROGEN COMPOUNDS
LIQUID WASTES
MEMBRANES
NONMETALS
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PERFORMANCE
SEPARATION PROCESSES
TRANSITION ELEMENT COMPOUNDS
TUBES
WASTE WATER
WASTES
WATER
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES
540220* -- Environment
Terrestrial-- Chemicals Monitoring & Transport-- (1990-)
CARBON
CARBOXYLIC ACIDS
CHALCOGENIDES
ELEMENTS
EVALUATION
FILTRATION
HYDROGEN COMPOUNDS
LIQUID WASTES
MEMBRANES
NONMETALS
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PERFORMANCE
SEPARATION PROCESSES
TRANSITION ELEMENT COMPOUNDS
TUBES
WASTE WATER
WASTES
WATER
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES