Corrosion behavior of a novel SiC/Al{sub 2}O{sub 3}/Al composite exposed to chloride environments

Journal Article · Sat Nov 01 04:00:00 EST 1997 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/1.1838092· OSTI ID:564082

Kolman, D G; Butt, D P ^[1]

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1. Los Alamos National Lab., NM (United States). Materials Corrosion and Environmental Effects Lab.

The electrochemical behavior of a new class of aluminum metal matrix composites produced by the direct metal oxidation technique, Lanxide AS-109(trademark), was detailed. The composite is 69% (by volume) SiC reinforcement, 24% oxidized metal (primarily Al{sub 2}O{sub 3}), and 7% retained aluminum alloy. The corrosion behavior of the SiC/Al{sub 2}O{sub 3}/Al composite was found to be dependent on NaCl concentration and pH. SiC/Al{sub 2}O{sub 3}/Al was susceptible to pitting of the Al alloy phase at open circuit during exposure to aerated and deaerated 0.6, 0.06, and 0.006 M NaCl solutions. In contrast, exposure to 6 {times} 10{sup {minus}4} M NaCl did not result in pitting at open circuit, and buffered borate solution (no chloride) did not yield pitting at any potential examined. The pitting potential of SiC/Al{sub 2}O{sub 3}/Al was estimated to decrease 80 mV per order of magnitude increase in NaCl concentration. Comparison of the composite to a model composite matrix material, Al 6061, revealed that the composite was more susceptible to localized corrosion than the matrix alloy alone which did not pit at open circuit in deaerated 0.6 M NaCl. Polarization resistance measurements in pH adjusted (pH 1 to 13) 0.6 M NaCl solutions revealed that the corrosion rate is minimized in neutral solution. Pits were neither confined to regions adjacent to SiC nor Al{sub 2}O{sub 3}, suggesting little galvanic effect of the reinforcing phases.

• Sponsoring Organization: USDOE, Washington, DC (United States)
• OSTI ID: 564082
• Journal Information: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 11 Vol. 144; ISSN 0013-4651; ISSN JESOAN
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ALUMINIUM
ALUMINIUM OXIDES
COMPOSITE MATERIALS
CORROSIVE EFFECTS
ELECTROCHEMICAL CORROSION
PH VALUE
PITTING CORROSION
SILICON CARBIDES
SODIUM CHLORIDES