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U.S. Department of Energy
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Chemistry control with morpholine at Beaver Valley Power Station

Technical Report ·
OSTI ID:5640465

Morpholine is a neutralizing amine commonly used in fossil steam plant condensate systems. Several nuclear plants added morpholine to increase the condensate pH when phosphate chemistry control was being used. When plants implemented AVT chemistry control, morpholine was not added to the secondary cycle of most nuclear plants in the United States. However, Beaver Valley has used morpholine in AVT chemistry control since initial operation in 1976. This study briefly describes the use of morpholine at Beaver Valley and reports levels of inorganic acids present in the steam cycle with and without morpholine additions. The makeup water is a significant source of the low levels of formic and acetic acids measured in the secondary cycle. The thermal decomposition of morpholine is a measurable but not a significant source of these two acids at Beaver Valley, except as measured in only one location in the cycle - the vapor space above the heater drain receiver tank water level. 16 refs.

Research Organization:
NUS Corp., Pittsburgh, PA (USA). Radiation Protection and Chemistry Services Dept.
OSTI ID:
5640465
Report Number(s):
EPRI-NP-4623; ON: TI86920385
Country of Publication:
United States
Language:
English