Platinum(II) acetate complexes in hydrogenation of unsaturated compounds

Journal Article · Thu Dec 20 04:00:00 EST 1979 · Bull. Acad. Sci. USSR, Div. Chem. Sci.; (United States)

DOI:https://doi.org/10.1007/BF00947402· OSTI ID:5622574

Berenblyum, A S; Goranskaya, T P; Mund, S L; Moiseev, I I

In order to further elucidate the effect of the ligand environment in the complexes of group VIII metals on the activity of H/sub 2/, the catalytic properties of Pt(II) compounds with oxygen-containing acido ligands was studied. The platinum(II) acetate complexes with aniline and triphenylphosphine were synthesized. IR spectral studies indicated that platinum(II) acetate formed complexes with either of the other compounds singly or together. Dimethylformamide(DMF) solutions of platinum acetate and its complexes with aniline and/or triphenylphosphine all absorb H/sub 2/ in the temperature range of 20 to 90/sup 0/C and at a H/sub 2/ pressure of 1 atm. After the absorption of H/sub 2/, the DMF solutions of (aniline)(triphenylphosphine)platinum(II)diacetate complex were found to catalyze the hydrogenaton of O/sub 2/ and 1,3-pentadiene.

• OSTI ID: 5622574
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci.; (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci.; (United States) Vol. 28:6; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACETATES
ADSORPTION
AMINES
ANILINE
AROMATICS
CARBOXYLIC ACID SALTS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
COMPLEXES
CRYOGENIC FLUIDS
DIENES
ELEMENTS
FLUIDS
HYDROCARBONS
HYDROGEN
HYDROGENATION
NONMETALS
ORGANIC COMPOUNDS
OXYGEN
PENTADIENES
PHOSPHINES
PHOSPHORUS COMPOUNDS
PLATINUM COMPLEXES
POLYENES
SORPTION
TRANSITION ELEMENT COMPLEXES