Dynamics of gas-phase reactions of muonium
Technical Report
·
OSTI ID:5617964
Applications of variational-transition-state theory with semiclassical adiabatic transmission coefficients to the reactions of muonium with H/sub 2/, D/sub 2/, F/sub 2/, and Cl/sub 2/ are reviewed. In addition, new calculations are presented for the Mu + Cl/sub 2/ and Br/sub 2/ reactions. The comparison of calculated rate constants and kinetic isotope effects (KIE's) with experiment is used as a test of the validity of semiempirical potential energy surfaces. Furthermore the VTST-plus-tunneling calculations allow an analysis of the KIE's that identifies those features of the potential which control the isotope effects.
- Research Organization:
- Chemical Dynamics Corp., Upper Marlboro, MD (USA)
- OSTI ID:
- 5617964
- Report Number(s):
- AD-A-185069/2/XAB
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
640303* -- Atomic
Molecular & Chemical Physics-- Positronium
Muonium
& Muonic & Mesic Atoms & Molecules
74 ATOMIC AND MOLECULAR PHYSICS
CHLORINE
DEUTERIUM
ELEMENTARY PARTICLES
ELEMENTS
FERMIONS
FLUORINE
HALOGENS
HYDROGEN
HYDROGEN ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LEPTONS
LIGHT NUCLEI
MESIC MOLECULES
MOLECULES
MUONIC MOLECULES
MUONIUM
MUONS
NONMETALS
NUCLEI
ODD-ODD NUCLEI
REACTION KINETICS
STABLE ISOTOPES
Molecular & Chemical Physics-- Positronium
Muonium
& Muonic & Mesic Atoms & Molecules
74 ATOMIC AND MOLECULAR PHYSICS
CHLORINE
DEUTERIUM
ELEMENTARY PARTICLES
ELEMENTS
FERMIONS
FLUORINE
HALOGENS
HYDROGEN
HYDROGEN ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LEPTONS
LIGHT NUCLEI
MESIC MOLECULES
MOLECULES
MUONIC MOLECULES
MUONIUM
MUONS
NONMETALS
NUCLEI
ODD-ODD NUCLEI
REACTION KINETICS
STABLE ISOTOPES