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Gas phase spectroscopy near the carbon K-edge

Conference ·
OSTI ID:5615410
;
Soft x-ray excitation involving C 1s electrons in CO, as well as aliphatic, and aromatic hydrocarbons is found to result in ionic fragmentation of the original molecule. The fragmentation pattern changes whether the C 1s electron gets ionized or excited into a Rydberg-like orbital, or into an unfilled molecular orbital. In this study we correlate the near edge C 1s absorption spectra with the observation of specific ionic fragments of the original molecules.
Research Organization:
Brookhaven National Lab., Upton, NY (USA); Exxon Research and Engineering Co., Linden, NJ (USA). Corporate Research Science Lab.
DOE Contract Number:
AC02-76CH00016
OSTI ID:
5615410
Report Number(s):
BNL-33895; CONF-8310172-3; ON: DE84002876
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400104* -- Spectral Procedures-- (-1987)
ABSORPTION SPECTRA
ACCELERATORS
CARBON
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CYCLIC ACCELERATORS
ELEMENTS
ENERGY-LEVEL TRANSITIONS
EXCITATION
IONIZATION
NONMETALS
NSLS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RADIATION SOURCES
SPECTRA
SPECTROSCOPY
SYNCHROTRON RADIATION SOURCES
SYNCHROTRONS
X-RAY SPECTROSCOPY