Reactions of the dirhenium(II) complexes Re/sub 2/X/sub 4/(dppm)/sub 2/ (X = Cl, Br; dppm = Ph/sub 2/PCH/sub 2/PPh/sub 2/) with isocyanides. 5. Mixed carbonyl-isocyanide and carbonyl-isocyanide-nitrile complexes of stoichiometry (Re/sub 2/Cl/sub 3/(dppm)/sub 2/(CO)(CNR)(L))PF/sub 6/ (R = t-Bu, xyl (Xylyl); L = t-BuNC, xylNC, MeCN, EtCN). Structural characterization of the cation (Cl/sub 2/(CO)Re(/mu/-dppm)/sub 2/ReCl (CN-t-Bu)/sub 2/)/sup +/
Journal Article
·
· Inorg. Chem.; (United States)
Several dirhenium (II) species that contain mixed sets of carbonyl, isocyanide, and/or nitrile ligands have been prepared from the reactions between Re/sub 2/Cl/sub 4/(dppm)/sub 2/(CO)(CNR) (dppm = Ph/sub 2/PCHPPh/sub 2/; R = t-Bu, xyl (xylyl)), and the appropriate ligands in the presence of TlPF/sub 6/. The crystal structures of these compounds are reported. The terminally-bound ligand noted in the complexes (Re/sub 2/Cl/sub 3/(dppm)/sub 2/(CO)(CN-t-Bu)/sub 2/)PF/sub 6/ and (Re/sub 2/CL/sub 3/(dppm)/sub 2/(CO)(CN-t-Bu)(CNxyl))PF/sub 6/ indicates structures that have not been previously reported. Complexes in which there are mixed sets of carbonyl, isocyanide, and nitrile ligands, viz. (Re/sub 2/Cl/sub 3/(dppm)/sub 2/(CO)(CNR)(CNR'))PF/sub 6/ are also reported. 20 refs., 1 fig., 5 tabs.
- Research Organization:
- Purdue Univ., West Lafayette, IN (USA)
- OSTI ID:
- 5614447
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 27:15; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Chemistry of Rh/sub 2/(CO)/sub 2/(Cl)/sub 2/(dppm)/sub 2/ and compounds derived therefrom: Structural characterization of Rh/sub 2/(CO)Cl/sub 4/(dppm)/sub 2/ and (Rh/sub 2/(CO)Cl/sub 3/(dppm)/sub 2/MeOH)(PF/sub 6/)
Dppm-Assisted synthesis and reactivity of bimetallic M-Mo, M-W, M-Co, and M-Mn (M = Pt, Pd) complexes. Crystal structure of [([eta][sup 2]-dppm)[ovr Pt([mu]-dppm)W](CO)[sub 2]Cp][PF[sub 6]][center dot]CH[sub 2]Cl[sub 2] (dppm = Ph[sub 2]PCH[sub 2]PPh[sub 2])
Homoleptic isocyanide complexes of ruthenium(III) and osmium(II)
Journal Article
·
Tue Nov 29 23:00:00 EST 1988
· Inorg. Chem.; (United States)
·
OSTI ID:5762053
Dppm-Assisted synthesis and reactivity of bimetallic M-Mo, M-W, M-Co, and M-Mn (M = Pt, Pd) complexes. Crystal structure of [([eta][sup 2]-dppm)[ovr Pt([mu]-dppm)W](CO)[sub 2]Cp][PF[sub 6]][center dot]CH[sub 2]Cl[sub 2] (dppm = Ph[sub 2]PCH[sub 2]PPh[sub 2])
Journal Article
·
Wed Apr 28 00:00:00 EDT 1993
· Inorganic Chemistry; (United States)
·
OSTI ID:6046945
Homoleptic isocyanide complexes of ruthenium(III) and osmium(II)
Journal Article
·
Wed Oct 09 00:00:00 EDT 1985
· Inorg. Chem.; (United States)
·
OSTI ID:5954389
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALKANES
AROMATICS
BARYONS
CARBONYLS
CHEMICAL PREPARATION
COMPLEXES
CRYSTAL STRUCTURE
DATA
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
HADRONS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
ISOCYANATES
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NITRILES
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PROTONS
RHENIUM COMPLEXES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALKANES
AROMATICS
BARYONS
CARBONYLS
CHEMICAL PREPARATION
COMPLEXES
CRYSTAL STRUCTURE
DATA
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
HADRONS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
ISOCYANATES
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NITRILES
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PROTONS
RHENIUM COMPLEXES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES