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Amazon capims (floating grassmats): A source of sup 13 C enriched methane to the troposphere

Journal Article · · Geophysical Research Letters (American Geophysical Union); (United States)
 [1];  [2];  [3];
  1. Florida State Univ., Tallahassee (USA)
  2. Univ. of New Hampshire, Durham (USA)
  3. Univ. of North Carolina, Chapel Hill (USA)
The {sup 13}C isotope composition of methane emitted to the troposphere from Amazon capims (floating grassmats) ranged from {minus}36.9 to {minus}48.0{per thousand} averaging {minus}44.4 {plus minus} 4.2{per thousand}. All pools of methane associated with the grassmats were {sup 13}C enriched; methane withdrawn from plant stems ranged from {minus}39 to {minus}49{per thousand} while bubbles stirred from the root mat averaged {minus}41.4{per thousand}. As the CH{sub 4} flux from these habitats makes up some 40% of the total flux from the Amazon flooplain, CH{sub 4} emissions form the region as a whole must be enriched in the heavy carbon isotope. Methane withdrawn from the stems of five genera of rooted macrophysics ranging in latitude from the Florida Everglades to the Alaskan Arctic exhibited {sup 13}C enrichment relative to the sedimentary methane bubble reservoir. Several hypotheses based upon isotopic fractionation by methane transport, oxidation and production processes are proposed to explain this phenomenon.
OSTI ID:
5608945
Journal Information:
Geophysical Research Letters (American Geophysical Union); (United States), Journal Name: Geophysical Research Letters (American Geophysical Union); (United States) Vol. 16:8; ISSN 0094-8276; ISSN GPRLA
Country of Publication:
United States
Language:
English