Transformations, lifetimes, and sources of NO2, HONO, and HNO3 in indoor environments

Journal Article · Mon Nov 01 04:00:00 EST 1993 · Journal of the Air and Waste Management Association; (United States)

OSTI ID:5608459

Spicer, C W; Kenny, D V; Ward, G F; Billick, I H ^[1]

---

1. Battelle, Columbus, OH (United States)

Recent research has demonstrated that nitrogen oxides are transformed to nitrogen acids in indoor environments, and that significant concentrations of nitrous acid are present in indoor air. The purpose of the study reported in this paper has been to investigate the sources, chemical transformations and lifetimes of nitrogen oxides and nitrogen acids under the conditions existing in buildings. An unoccupied single family residence was instrumented for monitoring of NO, NO2, NOy, HONO, HNO3, CO, temperature, relative humidity, and air exchange rate. For some experiments, NO2 and HONO were injected into the house to determine their removal rates and lifetimes. Other experiments investigated the emissions and transformations of nitrogen species from unvented natural gas appliances. We determined that HONO is formed by both direct emissions from combustion processes and reaction of NO2 with surfaces present indoors. Equilibrium considerations influence the relative contributions of these two sources to the indoor burden of HONO. We determined that the lifetimes of trace nitrogen species varied in the order NO approximately HONO > NO2 > HNO3. The lifetimes with respect to reactive processes are on the order of hours for NO and HONO, about an hour for NO2, and 30 minutes or less for HNO3. The rapid removal of NO2 and long lifetime of HONO suggest that HONO may represent a significant fraction of the oxidized nitrogen burden in indoor air.

• OSTI ID: 5608459
• Journal Information: Journal of the Air and Waste Management Association; (United States), Journal Name: Journal of the Air and Waste Management Association; (United States) Vol. 43:11; ISSN JAWAEB; ISSN 1047-3289
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
540120* -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (1990-)
AIR POLLUTION
BUILDINGS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
HYDROGEN COMPOUNDS
INDOOR AIR POLLUTION
INORGANIC ACIDS
KINETICS
LIFETIME
NITRIC ACID
NITROGEN COMPOUNDS
NITROGEN DIOXIDE
NITROGEN OXIDES
NITROUS ACID
OXIDES
OXYGEN COMPOUNDS
POLLUTION
POLLUTION SOURCES
REACTION KINETICS