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Title: Use of precalciners to remove alkali from raw materials in the cement industry. Quarterly technical progress report, November 1979-January 1980

Technical Report ·
DOI:https://doi.org/10.2172/5602497· OSTI ID:5602497

Experiments using the sulfate fusion technique have continued. High degrees of alkali removal have been achieved using CaSO/sub 4/ admixtures with added CaCl/sub 2/ and Mg(NO/sub 3/)/sub 2/. The presence of Mg/sup 2 +/ or Cl/sup -/ in the mixtures did not affect the phase separation significantly. There was considerable evidence for preferential migration of K/sup +/ into the sulfate phase, relative to Na/sup +/. A new technique, the powder drop method, was used to attempt to more closely simulate the alkali removal reactions which would occur in a reactor. Rapid removal of K/sup +/ from most minerals was shown to occur with a sulfate melt initially containing 20% Na/sub 2/SO/sub 4/ and 80% CaSO/sub 4/. However, in most cases, the Na/sup +/ content of the slag layer actually increased.

Research Organization:
Portland Cement Association, Skokie, IL (USA). Construction Technology Labs.
DOE Contract Number:
EM-78-C-02-4929
OSTI ID:
5602497
Report Number(s):
DOE/CS/40061-6
Country of Publication:
United States
Language:
English