Palladium in some selective oxidation reactions
Journal Article
·
· Acc. Chem. Res.; (United States)
Palladium (Pd) complexes catalyzed many different types of organic reactions because the metal is able to coordinate many different organic substrates and is effective in almost all fundamental organometallic reactions such as oxidative addition, reductive elimination, nucleophilic addition, insertion reactions, and beta-elimination. The effectiveness of Pd's catalytic power to promote the formation of 1,2-and 1,4-alkenes and dienes from 1,3-dienes ad other alkenes is discussed. Nucleophilic attack on (Pi-olefins)-, (Pi-alkyl)- and (o-alkyl) palladium complexes and oxidation cleavage are of importance in these reactions.
- Research Organization:
- Royal Inst. of Tech., Stockholm, Sweden
- OSTI ID:
- 5596856
- Journal Information:
- Acc. Chem. Res.; (United States), Journal Name: Acc. Chem. Res.; (United States) Vol. 16:9; ISSN ACHRE
- Country of Publication:
- United States
- Language:
- English
Similar Records
Multistep electron transfer in palladium-catalyzed aerobic oxidations via a metal macrocycle-quinone system
Palladium-catalyzed coupling of vinyl triflates with organostannanes. Synthetic and mechanistic studies
Palladium-catalyzed coupling reactions: mechanism of reductive elimination. Progress report, October 1, 1980-June 30, 1981. [Ethane elimination from dimethylpalladium, propenylbenzene from styrylmethylpalladium]
Journal Article
·
Wed Jun 20 00:00:00 EDT 1990
· Journal of the American Chemical Society; (USA)
·
OSTI ID:6653744
Palladium-catalyzed coupling of vinyl triflates with organostannanes. Synthetic and mechanistic studies
Journal Article
·
Wed May 28 00:00:00 EDT 1986
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5455974
Palladium-catalyzed coupling reactions: mechanism of reductive elimination. Progress report, October 1, 1980-June 30, 1981. [Ethane elimination from dimethylpalladium, propenylbenzene from styrylmethylpalladium]
Technical Report
·
Mon Jun 01 00:00:00 EDT 1981
·
OSTI ID:6293580
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKALI METAL COMPOUNDS
ALKENES
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DIENES
DOCUMENT TYPES
ELEMENTS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
LIGANDS
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
NONMETALS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
OXYGEN
PALLADIUM COMPLEXES
POLYENES
QUANTITY RATIO
REACTION INTERMEDIATES
REVIEWS
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKALI METAL COMPOUNDS
ALKENES
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DIENES
DOCUMENT TYPES
ELEMENTS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
LIGANDS
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
NONMETALS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
OXYGEN
PALLADIUM COMPLEXES
POLYENES
QUANTITY RATIO
REACTION INTERMEDIATES
REVIEWS
TRANSITION ELEMENT COMPLEXES