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pH-dependent toxicity of Cd, Cu, Ni, Pb and Zn to Ceriodaphnia dubia, Pimephales promelas, Hyalella azteca and Lumbriculus variegatus

Journal Article · · Environmental Toxicology and Chemistry; (United States)
; ;  [1];  [2]
  1. AScI Corp., Duluth, MN (United States)
  2. Environmental Research Lab., Duluth, MN (United States). Environmental Protection Agency

The speciation and bioavailability of metals are known to be affected by pH. Although many studies have focused on effects on metals of pH changes resulting from lake acidification, metal toxicity changes at higher pH values are of great interest to those performing effluent and sediment toxicity testing and toxicity identification evaluations (TIEs). In addition, most previous studies have addressed metal toxicity changes with pH to water-column organisms rather than to benthic or epibenthic species. The authors tested the acute toxicity of five metals (Cd, Cu, Ni, Pb, and Zn) to Ceriodaphnia dubia, Pimephales promelas, Hyalella azteca, and Lubriculus variegatus at three pH values in very hard reconstituted water. Toxicity of Cd, Ni, and zn was greatest at pH 8.3 and least at pH 6.3 to most of these species. Conversely, the toxicity of Cu and Pb was greatest at pH 6.3 and least at pH 8.3 to most of the species. The acute toxicity of most of the metals to Lumbriculus variegatus was very low and occasionally was above the aqueous solubility of the metal salts in the reconstituted water.

OSTI ID:
5592377
Journal Information:
Environmental Toxicology and Chemistry; (United States), Journal Name: Environmental Toxicology and Chemistry; (United States) Vol. 12:7; ISSN 0730-7268; ISSN ETOCDK
Country of Publication:
United States
Language:
English