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Radiation-induced cataphoretic isotope separation in He-Ne discharges

Thesis/Dissertation ·
OSTI ID:5585078
A feasibility study on separation of the Ne/sup 20/ and the Ne/sup 22/ isotope in a gaseous discharge using a radiation-induced cataphoretic separation technique was carried out, with negative results. The 0.6328 ..mu..m He-Ne laser radiation was the source used in the first phase of the work and a Ne fluorescent source was used in addition in the later part. The cataphoretic discharge usually contained in a He-Ne mixture with approximately equal quantities of Ne/sup 20/ and Ne/sup 22/. Preferential excitation of the one neon isotope was demonstrated, but selective excitation does not insure selective separation of the neon isotopes through cataphoretic action. Studies have shown that resonant radiation can produce a significant change in the ionization rate and the discharge current, and this effect has been termed both the Penning effect and, more recently, the Optogalvanic effect. Although cataphoretic action is known to be capable of significant separation of neon from helium in the discharge and preferential excitation has been achieved, it does not follow that cataphoretic separation of the neon isotope occurs. The main problem appears to be that under conditions favorable for cataphoretic separation of the helium and neon, the ion exchange reaction in the neon occurs too rapidly.
Research Organization:
Minnesota Univ., Minneapolis (USA)
OSTI ID:
5585078
Country of Publication:
United States
Language:
English