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U.S. Department of Energy
Office of Scientific and Technical Information

Research on the monolithic process of making A-15 superconducting materials

Conference ·
OSTI ID:5583463
It is possible to produce high T/sub c/ wires or tapes from the V-Ga system by a monolithic process in which an ingot is cast as a supersaturated solution of V and Ga, homogenized at elevated temperature, quenched to preserve the supersaturation, formed into a wire or tape, and finally heat treated at a relatively low temperature to precipitate the superconducting phase. To achieve exceptionally high critical temperatures, the precipitation reaction must be carried out at temperatures below approximately 750/sup 0/C. The measured critical temperature then becomes a function of the aging time, and reaches a maximum value as high as 14.8/sup 0/K in alloys containing 17 to 19 at. % Ga. The reason for the exceptionally high critical temperature when the precipitation is carried out at lower aging temperatures is not established, but may be plausibly interpreted as due to a thermodynamic tendency for small precipitates formed from highly supersaturated solid solutions to be rich in solute content.
Research Organization:
California Univ., Berkeley (USA). Lawrence Berkeley Lab.
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
5583463
Report Number(s):
LBL-10007; CONF-790815-33
Country of Publication:
United States
Language:
English