Solvated electron optical absorption spectra in liquid methylamine

Journal Article · Wed Feb 03 23:00:00 EST 1982 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100392a009· OSTI ID:5581864

Stupak, C M; Tuttle, Jr, T R; Golden, S

Solvated electron optical absorption spectra in liquid methylamine have been obtained by extrapolating relative absorbance data obtained from dilute lithium solutions to infinite dilution in lithium. These spectra are shown to be identical within experimental error with solvated electron spectra determined by using pulse radiolysis. Also, within experimental uncertainty all of the spectral profiles of solvated electron spectra in methylamine display shape stability. The effective number of solvent molecules which serve to localize the electron in methylamine is determined to be 0.83.

• Research Organization: Brandeis Univ., Waltham, MA
• OSTI ID: 5581864
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 86:3; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ABSORPTION SPECTRA
ALKALI METALS
AMINES
COMPARATIVE EVALUATIONS
DATA
ELECTRONS
ELEMENTARY PARTICLES
ELEMENTS
EXPERIMENTAL DATA
FERMIONS
FLUIDS
INFORMATION
LEPTONS
LIQUIDS
LITHIUM
METALS
METHYLAMINE
NUMERICAL DATA
ORGANIC COMPOUNDS
SOLVATED ELECTRONS
SPECTRA
SPECTROSCOPY