Surface structure of radical 3 times radical 3 R 30 degree Cl/Ni(111) determined using low-temperature angle-resolved photoemission extended fine structure
Journal Article
·
· Physical Review, B: Condensed Matter; (United States)
- Department of Chemistry, University of California, Berkeley, California 94720 (United States) Materials and Chemical Sciences Division, Lawrence Berkeley Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States)
A surface structural study of the {radical}3 {times} {radical}3 {ital R}30{degree} Cl/Ni(111) adsorbate system was made using low-temperature angle-resolved photoemission extended fine structure. The experiments were performed along two emission directions, (111) and (110), and at two temperatures, 120 and 300 K. The multiple-scattering spherical-wave analysis determined that the Cl atom adsorbs in the fcc threefold hollow site, 1.837(8) A above the first nickel layer, with a Cl-Ni bond length of 2.332(6) A, and an approximate 5% contraction between the first and the second nickel layers (the errors in parentheses are statistical standard deviations only).
- DOE Contract Number:
- AC03-76SF00098
- OSTI ID:
- 5579492
- Journal Information:
- Physical Review, B: Condensed Matter; (United States), Journal Name: Physical Review, B: Condensed Matter; (United States) Vol. 44:24; ISSN 0163-1829; ISSN PRBMD
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360102* -- Metals & Alloys-- Structure & Phase Studies
360104 -- Metals & Alloys-- Physical Properties
ADSORPTION
CHLORINE
CRYSTAL STRUCTURE
ELEMENTS
EMISSION
ENERGY LEVELS
HALOGENS
LAYERS
METALS
MICROSTRUCTURE
NICKEL
NONMETALS
PHOTOEMISSION
S STATES
SECONDARY EMISSION
SORPTION
SORPTIVE PROPERTIES
SURFACE PROPERTIES
TRANSITION ELEMENTS
360102* -- Metals & Alloys-- Structure & Phase Studies
360104 -- Metals & Alloys-- Physical Properties
ADSORPTION
CHLORINE
CRYSTAL STRUCTURE
ELEMENTS
EMISSION
ENERGY LEVELS
HALOGENS
LAYERS
METALS
MICROSTRUCTURE
NICKEL
NONMETALS
PHOTOEMISSION
S STATES
SECONDARY EMISSION
SORPTION
SORPTIVE PROPERTIES
SURFACE PROPERTIES
TRANSITION ELEMENTS