Centrifugal distortion and internal rotation analysis of the microwave spectrum of ethyl fluoride

Journal Article · Mon Mar 14 23:00:00 EST 1983 · J. Chem. Phys.; (United States)

DOI:https://doi.org/10.1063/1.445177· OSTI ID:5577050

Fliege, E; Dreizler, H; Demaison, J; Boucher, D; Burie, J; Dubrulle, A

The internal rotation fine structure of the microwave spectrum of ethyl fluoride CH/sub 3/CH/sub 2/F was resolved and analyzed in the ground state. The assignment of the high J lines was checked by a centrifugal distortion analysis. The barrier height V/sub 3/ determined from the ground state is 3349 +- 4 cal/mol.

• Research Organization: Abteilung Chemische Physik, Institut fuer Physikalische Chemie der Universitaet Kiel, D 2300 Kiel, West Germany
• OSTI ID: 5577050
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 78:6; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
CHARGED PARTICLES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DECOMPOSITION
DEUTERIUM
DISSOCIATION
HYDROGEN ISOTOPES
IONS
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
MASS SPECTROSCOPY
MOLECULAR IONS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
SPECTROSCOPY
STABLE ISOTOPES