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Study of molecular hydrogen dissociation at low keV energies

Thesis/Dissertation ·
OSTI ID:5577024
The dissociations of molecules are investigated theoretically for the diatomic breakup of H/sub 2//sup +/ following collisions between He/sup +/ and H/sub 2/, and investigated experimentally for the triatomic breakup of H/sub 3//sup +/ following H/sub 3//sup +/ collisions with He. A three particle coincidence experiment is proposed and analyzed for the purpose of studying the reaction He/sup +/ + H/sub 2/ ..-->.. He + H/sub 2//sup +/ ..-->.. He + H(2p) + H/sup +/. This experiment is designed to better define the final state of the system. The three particles to be detected in coincidence are: the scattered He, the proton, and the L/sub alpha/ photon including its polarization. A theory of measurement is developed that interprets the polarization data in terms of amplitudes and phase differences which are defined in the molecular frame. This theory includes the fine and hyperfine structure of the atomic excited states, the rotational states of the molecule, the orientation in the lab frame of the H/sub 2//sup +*/ after collision and the molecular potential energies to describe the final state following the dissociation of H/sub 2//sup +/. Since the general result is so complex, the radiation intensity equation is explicitly written out only for the three specific cases when the H/sub 2//sup +*/ is parallel to the lab X-, Y-, and Z-axes after the collision.
Research Organization:
Nebraska Univ., Lincoln (USA)
OSTI ID:
5577024
Country of Publication:
United States
Language:
English