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Preparation and structure of ([mu]-phenanthrene)- and ([mu]-pyrene)bis(tricarbonylchromium)

Journal Article · · Organometallics; (United States)
DOI:https://doi.org/10.1021/om00035a049· OSTI ID:5576478
; ; ;  [1]
  1. Univ. of North Dakota, Grand Forks, ND (United States)
The preparations of the bis(tricarbonylchromium) complexes of phenanthrene and pyrene are reported. These materials were characterized by spectroscopic means, including both their solution and solid CP/MAS NMR spectra. The X-ray crystal structure showed both complexes to have the anticipated anti orientation of the tricarbonylchromium moieties. In the phenanthrene complex, the rotomer conformations for the two tricarbonylchromium groups are different, whereas the pyrene complex has a center of inversion. 28 refs., 4 figs., 8 tabs.
OSTI ID:
5576478
Journal Information:
Organometallics; (United States), Journal Name: Organometallics; (United States) Vol. 12:11; ISSN 0276-7333; ISSN ORGND7
Country of Publication:
United States
Language:
English