Vibrational and rotational energy disposal in the H + D/sub 2/ reaction at 1. 3 Ev: surprisal analysis of experiments and computations
Technical Report
·
OSTI ID:5571691
Recent independent experimental determinations, by Zare and Valentini and their co-workers, of the HD product-state distribution are consistent with a common set of surprisal parameters: lambda/sub nu/ approx. = 2 and theta/sub r/ in the range 3-5. Analysis of the computational results of Blais and Truhlar suggest that a somewhat larger fraction of the available energy is channeled into rotation and that the orientation of the emergent HD molecule is constrained.
- Research Organization:
- Massachusetts Inst. of Tech., Cambridge (USA). Dept. of Chemistry
- OSTI ID:
- 5571691
- Report Number(s):
- AD-A-167156/9/XAB
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
640304* -- Atomic
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
ATOM COLLISIONS
ATOM-MOLECULE COLLISIONS
COLLISIONS
DEUTERIDES
DEUTERIUM
DEUTERIUM COMPOUNDS
DISTRIBUTION
ELEMENTS
ENERGY LEVELS
ENERGY RANGE
ENERGY TRANSFER
EV RANGE
EV RANGE 01-10
EXCITED STATES
HYDROGEN
HYDROGEN COMPOUNDS
HYDROGEN DEUTERIDE
HYDROGEN ISOTOPES
ISOTOPES
LIGHT NUCLEI
MOLECULE COLLISIONS
MOLECULES
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORIENTATION
ROTATIONAL STATES
STABLE ISOTOPES
VIBRATIONAL STATES
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
ATOM COLLISIONS
ATOM-MOLECULE COLLISIONS
COLLISIONS
DEUTERIDES
DEUTERIUM
DEUTERIUM COMPOUNDS
DISTRIBUTION
ELEMENTS
ENERGY LEVELS
ENERGY RANGE
ENERGY TRANSFER
EV RANGE
EV RANGE 01-10
EXCITED STATES
HYDROGEN
HYDROGEN COMPOUNDS
HYDROGEN DEUTERIDE
HYDROGEN ISOTOPES
ISOTOPES
LIGHT NUCLEI
MOLECULE COLLISIONS
MOLECULES
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORIENTATION
ROTATIONAL STATES
STABLE ISOTOPES
VIBRATIONAL STATES