(2-(5-Chloro-2-thienyl)vinyl)phosphonous dichloride and its derivatives

Journal Article · Wed Mar 19 23:00:00 EST 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5571244

Pudovik, A N; Khairullin, V K; Vasayanina, M A; Pokrovskaya, I K; Shagidullin, R R; Chernov, A N

By the reaction of 2-chloro-5-vinylthiophene with phosphorus pentachloride in phosphorus trichloride solution with the subsequent decomposition of the adduct formed with methyl phosphorochloridite they obtained (2-(5-chloro-2-thienyl)vinyl)phosphonous dichloride, and the reactions of this with ethyl iodide, acrylic and methacrylic acids, and carbon tetrachloride were studied. In (2-(5-chloro-2-thienyl)vinyl)phosphonous dichloride and the compounds prepared from it the vinyl protons are disposed in the trans position relative to each other.

• OSTI ID: 5571244
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:10; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACRYLIC ACID
ACTIVATION ENERGY
CARBON TETRACHLORIDE
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
COUPLING
COUPLING CONSTANTS
DOUBLE RESONANCE METHODS
ENERGY
ESTERS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
HYDROGEN 1
HYDROGEN ISOTOPES
INFRARED SPECTRA
INTERMEDIATE COUPLING
IODINATED ALIPHATIC HYDROCARBONS
ISOMERIZATION
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
METHACRYLIC ACID
MONOCARBOXYLIC ACIDS
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHONATES
PHOSPHONIC ACID ESTERS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
THIOPHENE