Redox reactions and complex formation of transplutonium elements in solutions

Journal Article · Wed Jan 01 04:00:00 EST 1986 · Sov. Radiochem. (Engl. Transl.); (United States)

OSTI ID:5569877

Krot, N N; Myasoedov, B F

This paper gives a brief analysis of the kinetics and mechanism of a number of redox processes and the complex formation of transplutonium elements in unusual oxidation states. The composition and strength of complexes of TPE with various addends have been determined. The new experimental data on the oxidation potentials of americium and berkelium ions in solutions are cited in abbreviated form. It follows from the data that in phosphoric acid solutions, when the H/sub 3/PO/sub 4/ concentration is increased from 10 to 15 M, the oxidation potential of the couple Am(IV)-Am(III) decreases. The oxidation potentials of the couples Am(VI)-Am(V), Cm(V)-Cm(IV), and Bk(IV)Bk(III) are also presented.

• OSTI ID: 5569877
• Journal Information: Sov. Radiochem. (Engl. Transl.); (United States), Journal Name: Sov. Radiochem. (Engl. Transl.); (United States) Vol. 27:3; ISSN SVRDA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102* -- Chemical & Spectral Procedures
ACTINIDE COMPLEXES
ALKALI METAL COMPOUNDS
AMERICIUM COMPLEXES
BERKELIUM COMPLEXES
CALIFORNIUM COMPLEXES
CHEMICAL COMPOSITION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
COMPLEXOMETRY
CURIUM COMPLEXES
DATA
EINSTEINIUM COMPLEXES
ELEMENTS
EXPERIMENTAL DATA
EXTRACTION
FERMIUM COMPLEXES
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INFORMATION
INORGANIC ACIDS
KINETICS
LAWRENCIUM COMPLEXES
MENDELEVIUM COMPLEXES
NITRIC ACID
NOBELIUM COMPLEXES
NUMERICAL DATA
OXIDATION
PHOSPHORIC ACID
PHOSPHORUS COMPOUNDS
POTASSIUM COMPOUNDS
POTASSIUM TUNGSTATES
QUANTITY RATIO
REACTION KINETICS
REDOX POTENTIAL
REDOX REACTIONS
REDUCTION
SEPARATION PROCESSES
SOLVENT EXTRACTION
TRANSPLUTONIUM COMPOUNDS
TRANSPLUTONIUM ELEMENTS
TRANSURANIUM COMPLEXES
TRANSURANIUM COMPOUNDS
TRANSURANIUM ELEMENTS
TUNGSTATES
VALENCE