Carboxymethylated polyethylenimine-polymethylenepolyphenylene isocyanate chelating ion exchange resin preconcentration for inductively coupled plasma spectrometry

Journal Article · Sun Jun 01 04:00:00 EDT 1986 · Anal. Chem.; (United States)

DOI:https://doi.org/10.1021/ac00298a018· OSTI ID:5569727

Horvath, A; Barnes, R M

A carboxymethylated polyethylenimine-polylmethylenepolyphenylene isocyanate chelating ion exchange resin was prepared, characterized, and used for metals preconcentration for inductively coupled plasma spectrometry. The uptake of copper, cadmium, lead, and zinc by the resin was quantitative in the presence of high concentrations of ammonium, calcium, magnesium, potassium, sodium, and acetate and citrate salts. These metals could be collected from artificial seawater, Dead Sea water, and dissolved bone with a recovery of nearly 100%. The resin also chelates heavy metals and rare earths. Complexed metals can be eluted from the resin column with strong acids. The resin does not change volume with ionic form changes and can be regenerated for repeated use.

• Research Organization: Univ. of Massachusetts, Amherst
• OSTI ID: 5569727
• Journal Information: Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 58:7; ISSN ANCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400104* -- Spectral Procedures-- (-1987)
400105 -- Separation Procedures
ANIMAL TISSUES
BODY
BONE TISSUES
CADMIUM
CHELATES
CHEMICAL ANALYSIS
COMPLEXES
CONNECTIVE TISSUE
COPPER
DATA
EFFICIENCY
ELEMENTS
EMISSION SPECTROSCOPY
EXPERIMENTAL DATA
HYDROGEN COMPOUNDS
INFORMATION
ION EXCHANGE
ION EXCHANGE MATERIALS
LEAD
LIGANDS
MATERIALS
METALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
PETROCHEMICALS
PETROLEUM PRODUCTS
PLASMA
POLYMERS
QUANTITATIVE CHEMICAL ANALYSIS
RESINS
SAMPLE PREPARATION
SEAWATER
SEPARATION PROCESSES
SPECTROSCOPY
TISSUES
TRANSITION ELEMENTS
WATER
ZINC