Characterization of inorganic salt particles by Raman spectroscopy
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
Raman spectra have been obtained for single aerosol particles levitated in an electrodynamic cell. The particles are composed of common inorganic salts such as sulfates, nitrates, phosphates and chromates in either pure or mixed form. The Raman vibrational frequencies observed for these compounds present in aerosol particles are found to be in good agreement with those of bulk samples. Moreover, the high resolution (±1 cm-1) developed in this work has made it possible to identify hydrated or mixed salts, which may be present in ambient aerosols under a variety of atmospheric conditions. It is shown that the Raman technique is a unique and non-destructive method for physical and chemical characterization of aerosol particles.
- Research Organization:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC02-76CH00016
- OSTI ID:
- 5564646
- Report Number(s):
- BNL--46378; CONF-910742--1; ON: DE91015836
- Journal Information:
- Journal of Aerosol Science, Journal Name: Journal of Aerosol Science Journal Issue: 5 Vol. 20; ISSN 0021-8502
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400102* -- Chemical & Spectral Procedures
54 ENVIRONMENTAL SCIENCES
540110
540120 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (1990-)
ABSORPTION
AEROSOLS
ATMOSPHERIC CHEMISTRY
CHEMICAL COMPOSITION
CHEMISTRY
COLLOIDS
DISPERSIONS
LASER SPECTROSCOPY
LEVITATION
PARTICLES
PARTICULATES
RAMAN SPECTRA
RESONANCE ABSORPTION
SOLS
SPECTRA
SPECTROSCOPY