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Title: Use of controlled release herbicides in waste burial sites

Conference ·
OSTI ID:5562121

Controlled-release formulations of herbicides have been applied to the soil in the manner traditional for herbicides: on the surface or mixed into the top few inches of soil. The controlled-release formulation allows another option that we propose to use: to place herbicides, contained in controlled-release formulations, in a layer at least a foot below the surface of the soil, in order to prevent root penetration below that level. Ideally, the herbicide will prevent root tip cell division but will not translocate within the plant, thus assuring that the plant will survive, preserving the ground cover. Trifluralin is one of the herbicides which does not translocate and was chosen for use in this study. A number of applications for this technology are possible; particularly in waste management. In the present studies, we used two different forms of polymeric carrier/delivery (PCD) systems to investigate the controlled release of herbicides. In the initial study, a sheet was made of homogeneous mixtures of an individual polymer and trifluralin. We made several of these sheets, using a different polymer each time (with trifluralin) to compare release rates from the various polymers. We also fabricated cylindrical pellets in two sizes from mixtures of Profax/sup a/ PS-1600 polypropylene and trifluralin, formulated to determine the interaction of PCD systems with soil. Also developed is a trifluralin-releasing device with a theoretical effective lifetime approaching 100 years. The system was designed specifically to protect the asphalt layer or clay/aggregate barriers on uranium mill tailings piles. PCD devices composed of pellets could also be implanted over burial sites for radioactive and/or toxic materials, preventing translocation of those materials to plant shoots, and thence into the biosphere.

Research Organization:
Pacific Northwest Lab., Richland, WA (USA)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
5562121
Report Number(s):
PNL-SA-9503; CONF-810765-2; ON: DE82006167; TRN: 82-007833
Resource Relation:
Conference: 8. international symposium on controlled release of bioactive materials, Fort Lauderdale, FL, USA, 26 Jul 1981
Country of Publication:
United States
Language:
English