Preparation and crystal structure of Na sub 3 SbO(PO sub 4 ) sub 2
- Universite de Nantes (France)
- Faculte des Sciences et Techniques, Abidjan (Ivory Coast)
The single phase compound Na{sub 3}SbO(PO{sub 4}){sub 2} was prepared by a solid state reaction. It crystallizes in the orthorhombic system, space group P2{sub 1}2{sub 1}2{sub 1} with a = 6.964(1) {angstrom}, b = 9.284(2) {angstrom}, c = 12.425(2) {angstrom}, Z = 4. The structure was determined from 968 reflections collected on a Nonius CAD4 automatic diffractometer with MoK{alpha} radiation. The final R index and weighted R{sub w} index are 0.031 and 0.039, respectively. The structure is built up from strings of corner-sharing SbO{sub 6} octahedra to which phosphate groups are linked by two of their vertices. These chains, running parallel to the a-axis, are separated from each other by sodium atoms.
- OSTI ID:
- 5559233
- Journal Information:
- Journal of Solid State Chemistry; (USA), Journal Name: Journal of Solid State Chemistry; (USA) Vol. 90:2; ISSN JSSCB; ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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360601* -- Other Materials-- Preparation & Manufacture
360602 -- Other Materials-- Structure & Phase Studies
ALKALI METAL COMPOUNDS
ANTIMONY COMPOUNDS
ANTIMONY OXIDES
CHALCOGENIDES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
DATA ANALYSIS
EXPERIMENTAL DATA
INFORMATION
NUMERICAL DATA
ORTHORHOMBIC LATTICES
OXIDES
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
SODIUM COMPOUNDS
SODIUM PHOSPHATES
SPACE GROUPS