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Title: Ln(Fe/sup 3 +/M/sup 2 +/)O/sub 4/ compounds with layer structure (Ln: Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn)

Journal Article · · J. Solid State Chem.; (United States)

A series of new compounds Ln(Fe/sup 3 +/M/sup 2 +/)O/sub 4/ (Ln : Y, Er, Tm, Yb, and Lu, M : Mg, Mn, Co, Cu, and Zn) were successfully synthesized and their lattice constants were determined. These compounds have the same crystal structure as YbFe/sub 2/O/sub 4/ and Fe/sup 3 +/ and M/sup 2 +/ are both surrounded by five oxygen ions forming a trigonal bipyramid. The synthetic conditions are presented. They are strongly dependent upon the constituent cations of the compound.

Research Organization:
National Inst. for Research in Inorganic Materials, Japan
OSTI ID:
5555332
Journal Information:
J. Solid State Chem.; (United States), Vol. 40:1
Country of Publication:
United States
Language:
English