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Observation of selected molecular-orbital x rays in coincidence with separated-atom K x rays

Journal Article · · Phys. Rev. Lett.; (United States)
A cascade relationship between molecular-orbital (MO) and separated-atom x rays has been utilized to study selected MO transitions. Depending on the mechanism of vacancy production, the observed MO spectra are interpreted as reflecting 2psigma ..-->.. 1ssigma transitions or a mixture of 2psigma ..-->.. 1ssigma and 2p..pi.. ..-->.. 1ssigma transitions. The coincidence selection also directly corroborates a previous assignment of MO transitions to the 2psigma state.
Research Organization:
A. W. Wright Structure Laboratory, Yale University, New Haven, Connecticut 06520
DOE Contract Number:
EY-76-C-02-3074
OSTI ID:
5535229
Journal Information:
Phys. Rev. Lett.; (United States), Journal Name: Phys. Rev. Lett.; (United States) Vol. 44:6; ISSN PRLTA
Country of Publication:
United States
Language:
English