Photoreactions of the triruthenium cluster Ru/sub 3/(CO)/sub 12/ and substituted analogues
Journal Article
·
· J. Am. Chem. Soc.; (United States)
Reported is a comprehensive investigation of the medium, ligand, and wavelength effects on the quantum yields and flash photolysis kinetics for the photosubstitution reactions of the trinuclear ruthenium cluster Ru/sub 3/(CO)/sub 12/. Also described are some related studies of the substituted clusters Ru/sub 3/(CO)/sub 12-n/L/sub n/(L = P(OCH/sub 3/)/sub 3/, PPh/sub 3/, P(p-totyl)/sub 3/, or P(O(0-totyl)/sub 3/). These results are interpreted in terms of a model for Ru/sub 3/(CO)/sub 12/ photochemistry.
- Research Organization:
- Univ. of California, Santa Barbara
- OSTI ID:
- 5532274
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 108:8; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
Similar Records
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Reaction dynamics of photosubstitution intermediates of the triruthenium cluster Ru sub 3 (CO) sub 12 as studied by flash photolysis with infrared detection
Journal Article
·
Wed Jul 15 00:00:00 EDT 1987
· Inorg. Chem.; (United States)
·
OSTI ID:5648488
Photoreactions of the triruthenium cluster HRu sub 3 (CO) sub 10 (. mu. -COCH sub 3 ). Isomerization of the bridging alkylidyne ligand and competing ligand substitutions
Journal Article
·
Tue Jan 17 23:00:00 EST 1989
· Journal of the American Chemical Society; (USA)
·
OSTI ID:5043062
Reaction dynamics of photosubstitution intermediates of the triruthenium cluster Ru sub 3 (CO) sub 12 as studied by flash photolysis with infrared detection
Journal Article
·
Wed Sep 06 00:00:00 EDT 1989
· Inorganic Chemistry; (USA)
·
OSTI ID:6985518
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
CARBONYLS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
EFFICIENCY
ENERGY LEVELS
EXCITED STATES
EXPERIMENTAL DATA
INFORMATION
KINETICS
LIGANDS
MATHEMATICAL MODELS
NUMERICAL DATA
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
QUANTUM EFFICIENCY
REACTION INTERMEDIATES
REACTION KINETICS
RUTHENIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
WAVELENGTHS
400500* -- Photochemistry
CARBONYLS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
EFFICIENCY
ENERGY LEVELS
EXCITED STATES
EXPERIMENTAL DATA
INFORMATION
KINETICS
LIGANDS
MATHEMATICAL MODELS
NUMERICAL DATA
PHOTOCHEMICAL REACTIONS
PHOTOCHEMISTRY
QUANTUM EFFICIENCY
REACTION INTERMEDIATES
REACTION KINETICS
RUTHENIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
WAVELENGTHS