Top down viewing of the inductively coupled plasma using a dual grating, direct reading spectrograph and an all mirror optical system
Using an all-mirror optical system, an inductively coupled plasma is viewed top down and the light is directed to a dual grating, direct reading spectrograph. Top down viewing of the plasma, with masking of the image of the argon plasma torus at the spectrograph entrance slit, significantly reduces background signal from the source and permits the use of the depth of field of the optical system to achieve compromise conditions for viewing the plasma. Light from the plasma source is introduced to the optical system by means of a mirror situated directly over the plasma. The system is exhausted in such a way that cool air flowing past the mirror forms a thermal barrier between the mirror and the plasma. Elements such as copper and lead have atomic and ionic lines which tend to exhibit self absorption when viewed top down through the cooler ground state atoms in the plume of the plasma. One of the approaches to this problem is to shear off the plume of the plasma with a jet of air directed across the tip of the plasma. A second approach is to make use of the dual grating, direct reading spectrograph and real-time computer system which easily permits the setting of alternate lines for each element so that self absorption and matrix effects are minimized. The design of the dual-grating, direct-reading spectrograph allows for the mounting of more than 200 13-mm-dia photomultiplier tubes along the focal curves. In an effort to demonstrate the use of fiber optics as a viable technique for the closer placement of exit slits, a red sensitive photomultiplier tube was coupled with a 30-cm fiber-optic ribbon to detect light from the Li 670.784 nm line on the focal curve. It was successful and had the added advantages of absorbing second-order ultraviolet light.
- Research Organization:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Colorado School of Mines, Golden (USA). Dept. of Physics; Southwestern at Memphis, TN (USA). Dept. of Physics
- DOE Contract Number:
- W-7405-ENG-36
- OSTI ID:
- 5528979
- Report Number(s):
- LA-UR-79-3238; CONF-800110-1; TRN: 80-004576
- Resource Relation:
- Conference: International conference on developments in atomic plasma spectrochemical analyses, San Juan, Puerto Rico, 7 Jan 1980
- Country of Publication:
- United States
- Language:
- English
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