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Facile-radioiododemetallation reactions for the convenient preparation of radioiodinated compounds

Journal Article · · Synth. Commun.; (United States)
Several new methods for the preparation of vinyl iodides via mercuration and thallation reactions of vinylboronic acids have been explored. Chloramine-T oxidation of alkylvinylmercury iodides or iodide treatment of alkylvinylthallium trifluoroacetate substrates, prepared from the corresponding alkylvinylboronic acid and thallic trifluoroacetate, yields the corresponding alkylvinyl iodides. These methods are also efficient for the synthesis of the corresponding radioiodinated compounds. 21 references.
Research Organization:
Oak Ridge National Lab., TN
DOE Contract Number:
AC05-84OR21400
OSTI ID:
5527353
Journal Information:
Synth. Commun.; (United States), Journal Name: Synth. Commun.; (United States) Vol. 15:4; ISSN SYNCA
Country of Publication:
United States
Language:
English