Electrochemical cell and method of assembly. [LiAl/LiCl-KCl/Li/sub 2/FeS/sub 2/]
A method of preparing an electrochemical cell is disclosed which permits the assembly to be accomplished in air. The cell includes a metal sulfide as the positive electrode reactant, lithium alloy as the negative electrode reactant, and an alkali metal; molten salt electrolyte. Positive electrode reactant is introduced as Li/sub 2/-FeS/sub 2/, a single-phase compound produced by the reaction of Li/sub 2/S and FeS. The use of this compound permits introduction of lithium in an oxidized form. Additional lithium can be introduced in the negative electrode structure enclosed within an aluminum foil envelope between layers of porous aluminum. Molten salt electrolyte is added after assembly and evacuation of the cell by including an interelectrode separator that has been prewet with an organic solution of KCl.
- Assignee:
- Dept. of Energy
- Patent Number(s):
- US 4172926
- OSTI ID:
- 5526287
- Resource Relation:
- Patent File Date: Filed date 29 Jun 1978; Other Information: PAT-APPL-920,414
- Country of Publication:
- United States
- Language:
- English
Similar Records
Electrochemical cell and method of assembly
High-performance batteries for off-peak energy storage and electric-vehicle propulsion. Progress report, January--March 1976. [Li--Al/LiCl--KCl/FeS or FeS/sub 2/; some work on CaAl/sub 2/, Ca/sub 2/Si, and Mg anodes and FeS, Fe/sub 3/O/sub 4/ and FeS/sub 2/ cathodes; ANL]
Related Subjects
LITHIUM-SULFUR BATTERIES
ANODES
CATHODES
FABRICATION
ALUMINIUM
ALUMINIUM BASE ALLOYS
BINARY ALLOY SYSTEMS
ELECTRIC-POWERED VEHICLES
IRON SULFIDES
LITHIUM ALLOYS
LITHIUM CHLORIDES
LITHIUM SULFIDES
OFF-PEAK ENERGY STORAGE
POTASSIUM CHLORIDES
ALKALI METAL COMPOUNDS
ALLOY SYSTEMS
ALLOYS
ALUMINIUM ALLOYS
CHALCOGENIDES
CHLORIDES
CHLORINE COMPOUNDS
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTRODES
ELEMENTS
ENERGY STORAGE
ENERGY STORAGE SYSTEMS
HALIDES
HALOGEN COMPOUNDS
IRON COMPOUNDS
LITHIUM COMPOUNDS
LITHIUM HALIDES
METAL-NONMETAL BATTERIES
METALS
POTASSIUM COMPOUNDS
STORAGE
SULFIDES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
VEHICLES
250901* - Energy Storage- Batteries- Design & Development
250903 - Energy Storage- Batteries- Materials
Components
& Auxiliaries