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Viscoelastic behavior of molten polymers in porous media

Journal Article · · AIChE J.; (United States)

The modification of the Blake-Kozeny equation for porous media flow using the power law has been shown to hold for molten polymers as well as for the previous cases for polymer solutions. The present work extended the correlation of friction factor with Reynolds number an additional 3 decades. Also, it was shown that the modified Blake-Kozeny equation broke down when bed shear rates were in the range of excessive curvature on the polymer flow curves (shear stress-shear rate). In such cases, it is suggested that the Newtonian Blake-equation, together with apparent viscosity data, could be used to correlate such porous media flow of non-Newtonians. Appearance of viscoelastic effects at the critical Deborah number value of 0.05 predicted earlier were not found to hold. The data of the present investigation show that such a critical value must be at least 0.19 or even higher. This result helps to resolve partially the anomalous results obtained by previous investigators. (20 refs.)

Research Organization:
Newark Coll. Eng.
OSTI ID:
5518282
Journal Information:
AIChE J.; (United States), Journal Name: AIChE J.; (United States) Vol. 17:2; ISSN AICEA
Country of Publication:
United States
Language:
English