Crossed molecular beam studies of ion-molecule reactions
Thesis/Dissertation
·
OSTI ID:5515052
A crossed molecular beam instrument is employed to study the energy and angular resolved scattering of the products of a number of ion-molecular reactions. The reactions studied are proton transfer from formyl cation to water, methanol and ethanol, and proton transfer from hydronium cation to methanol and ethanol. Relative collision energies range from a few tenths of an eV to several eV. Reactant ion beams are produced by electron impact or chemical ionization while neutral reactants are seeded in H/sub 2/, which is then expanded in a supersonic molecular beam source. Product ions are energy and mass analyzed and the raw data is transformed to center of mass, doubly-differential relative cross-sections.
- Research Organization:
- Rochester Univ., NY (USA)
- OSTI ID:
- 5515052
- Country of Publication:
- United States
- Language:
- English
Similar Records
Crossed molecular beam studies of some ion molecule reactions of C/sup +/ and CH/sub 3//sup +/
Translational energy-resolved collisionally activated methyl cation transfer from protonated methane to argon, krypton, and xenon and from protonated fluoromethane to argon and molecular oxygen
New crossed-beam apparatus for the study of ion--molecule collision processes
Thesis/Dissertation
·
Tue Dec 31 23:00:00 EST 1985
·
OSTI ID:7019621
Translational energy-resolved collisionally activated methyl cation transfer from protonated methane to argon, krypton, and xenon and from protonated fluoromethane to argon and molecular oxygen
Journal Article
·
Wed Oct 28 23:00:00 EST 1992
· Journal of Physical Chemistry
·
OSTI ID:458806
New crossed-beam apparatus for the study of ion--molecule collision processes
Journal Article
·
Wed Dec 31 23:00:00 EST 1975
· Rev. Sci. Instrum., v. 47, no. 1, pp. 15-26
·
OSTI ID:4077127
Related Subjects
640301* -- Atomic
Molecular & Chemical Physics-- Beams & their Reactions
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
ACYL RADICALS
ALCOHOLS
ANGULAR DISTRIBUTION
BEAMS
COLLIDING BEAMS
COLLISIONS
CROSS SECTIONS
DATA
DIFFERENTIAL CROSS SECTIONS
DISTRIBUTION
ELEMENTS
ENERGY RESOLUTION
ETHANOL
EXPERIMENTAL DATA
FLUID FLOW
FORMYL RADICALS
HYDROGEN
HYDROGEN COMPOUNDS
HYDRONIUM RADICALS
HYDROXY COMPOUNDS
INFORMATION
ION COLLISIONS
ION-MOLECULE COLLISIONS
METHANOL
MOLECULAR BEAMS
MOLECULE COLLISIONS
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
RADICALS
RESOLUTION
SCATTERING
SUPERSONIC FLOW
WATER
Molecular & Chemical Physics-- Beams & their Reactions
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
ACYL RADICALS
ALCOHOLS
ANGULAR DISTRIBUTION
BEAMS
COLLIDING BEAMS
COLLISIONS
CROSS SECTIONS
DATA
DIFFERENTIAL CROSS SECTIONS
DISTRIBUTION
ELEMENTS
ENERGY RESOLUTION
ETHANOL
EXPERIMENTAL DATA
FLUID FLOW
FORMYL RADICALS
HYDROGEN
HYDROGEN COMPOUNDS
HYDRONIUM RADICALS
HYDROXY COMPOUNDS
INFORMATION
ION COLLISIONS
ION-MOLECULE COLLISIONS
METHANOL
MOLECULAR BEAMS
MOLECULE COLLISIONS
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
RADICALS
RESOLUTION
SCATTERING
SUPERSONIC FLOW
WATER