Catalyst and reactor development for a liquid phase Fischer-Tropsch process
The preparation, characterization, and performance of a range of metal catalysts for use in slurry phase Fischer-Tropsch technology was investigated with the objective of developing new compositions with improved selectivity for gasoline and diesel fuel range hydrocarbons. A series of conventional catalysts was identified for testing for both gas and slurry phases. A gas phase screening protocol was set up to allow reasonably rapid determination of each catalyst's synthesis gas conversion characteristic over a range of operating conditions. The catalysts selected represented a range of catalytic metals known to promote conversion of synthesis gas to hydrocarbon liquids. Both precipitates and supported variations of these metals were studied. Catalysts studied include: ruthenium-based catalysts with osmium, and cobalt carbonyl supported on zirconia promoted. 23 refs., 2 figs., 10 tabs.
- Research Organization:
- Air Products and Chemicals, Inc., Allentown, PA (USA)
- Sponsoring Organization:
- DOE/FE
- DOE Contract Number:
- AC22-80PC30021
- OSTI ID:
- 5507414
- Report Number(s):
- DOE/PC/30021-T21; ON: DE90002793
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
090121* -- Hydrocarbon Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMICAL REACTORS
COBALT
DISPERSIONS
DOCUMENT TYPES
ELEMENTS
FISCHER-TROPSCH SYNTHESIS
METALS
MIXTURES
OSMIUM
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
PROGRESS REPORT
RUTHENIUM
SLURRIES
SUSPENSIONS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES
10 SYNTHETIC FUELS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMICAL REACTORS
COBALT
DISPERSIONS
DOCUMENT TYPES
ELEMENTS
FISCHER-TROPSCH SYNTHESIS
METALS
MIXTURES
OSMIUM
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
PROGRESS REPORT
RUTHENIUM
SLURRIES
SUSPENSIONS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES