Catalyst and reactor development for a liquid phase Fischer-Tropsch process
The preparation, characterization, and performance of a range of metal catalysts for use in slurry phase Fischer-Tropsch technology was investigated with the objective of developing new compositions with improved selectivity for gasoline and diesel fuel range hydrocarbons. A series of conventional catalysts was identified for testing for both gas and slurry phases. A gas phase screening protocol was set up to allow reasonably rapid determination of each catalyst's synthesis gas conversion characteristic over a range of operating conditions. The catalysts selected represented a range of catalytic metals known to promote conversion of synthesis gas to hydrocarbon liquids. Both precipitates and supported variations of these metals were studied. Catalysts studied include: ruthenium-based catalysts with osmium, and cobalt carbonyl supported on zirconia promoted. 23 refs., 2 figs., 10 tabs.
- Research Organization:
- Air Products and Chemicals, Inc., Allentown, PA (USA)
- Sponsoring Organization:
- DOE/FE
- DOE Contract Number:
- AC22-80PC30021
- OSTI ID:
- 5507414
- Report Number(s):
- DOE/PC/30021-T21; ON: DE90002793
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
10 SYNTHETIC FUELS
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMICAL REACTORS
COBALT
DISPERSIONS
DOCUMENT TYPES
ELEMENTS
FISCHER-TROPSCH SYNTHESIS
METALS
MIXTURES
OSMIUM
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
PROGRESS REPORT
RUTHENIUM
SLURRIES
SUSPENSIONS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES