Synthesis and characterization of hexakis(alkyl isocyanide) and hexakis(aryl isocyanide) complexes of technetium(I)

Journal Article · Wed Sep 28 00:00:00 EDT 1983 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic00162a007· OSTI ID:5506629

Abrams, M J ^[1]; Davison, A; Jones, A G; Costello, C E; Pang, H

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1. Massachusetts Inst. of Tech., Cambridge

The complexes, hexakis(alkyl isocyanide) technetium(I) hexafluorophosphate (Tc(CNR)/sub 6/)PF/sub 6/ (where R = tert-butyl, methyl, cyclohexyl, and phenyl), have been prepared by reduction of the pertechnetate ion with aqueous sodium dithionite (Na/sub 2/S/sub 2/O/sub 4/) in the presence of the isocyanide ligands. These complexes have been characterized by elemental analysis, optical, ir, and /sup 1/H NMR spectroscopy, conductance, cyclic voltammetry, and field desorption mass spectrometry.

• OSTI ID: 5506629
• Journal Information: Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 22:20; ISSN INOCA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
550601 -- Medicine-- Unsealed Radionuclides in Diagnostics
62 RADIOLOGY AND NUCLEAR MEDICINE
ALKALI METAL COMPOUNDS
ALKANES
AMMONIUM COMPOUNDS
AQUEOUS SOLUTIONS
AROMATICS
CHEMICAL PREPARATION
COMPARATIVE EVALUATIONS
COMPLEXES
CYANIDES
CYCLOALKANES
DATA
DISPERSIONS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
FLUORINE COMPOUNDS
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
INFRARED SPECTRA
MASS SPECTRA
MEASURING INSTRUMENTS
MIXTURES
NMR SPECTRA
NUMERICAL DATA
OPTICAL SPECTROMETERS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PERTECHNETATES
PH VALUE
PHOSPHATES
PHOSPHORUS COMPOUNDS
PHYSICAL PROPERTIES
RECRYSTALLIZATION
SODIUM COMPOUNDS
SOLUTIONS
SPECTRA
SPECTROMETERS
STRUCTURAL CHEMICAL ANALYSIS
SULFUR COMPOUNDS
SYNTHESIS
TECHNETIUM COMPLEXES
TECHNETIUM COMPOUNDS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
VOLTAMETRY