Pulsed laser deposition of diamond-like carbon thin films: Ablation dynamics and growth

Book · Mon Dec 01 04:00:00 EST 1997

OSTI ID:549811

Yang, P; Zhang, Z J; Hu, J; Lieber, C M ^[1]

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1. Harvard Univ., Cambridge, MA (United States)

Thin films of diamond-like carbon have been grown by pulsed laser deposition using a Nd:YAG laser at 532 nm. Time-of-flight mass spectroscopy was used to investigate the effects of laser power density and background gas pressure on the plume characteristics including the species in the plume and the kinetic energy distribution of each species. The authors found that with increasing laser power density (1) the relative amount of C+ ions increases, (2) the kinetic energy distributions of C+ get broader and can be deconvoluted into fast and slow components, and (3) the kinetic energy of the fast component of C+ ions increases from several to 40 eV. The resistivity and the local carbon bonding in films grown under these same conditions were also characterized. It was found that there is direct correlation between the characteristics of fast part of C+ ions in the plume and the diamond-like properties of the thin films. Under optimal growth conditions diamond-like carbon films with a large fraction of sp{sup 3} bonding can be prepared, although the maximum fraction appears to saturate at 70%. The implications of these results are discussed.

• OSTI ID: 549811
• Report Number(s): CONF-961202--; ISBN 1-55899-342-8
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ABLATION
CARBON
EXPERIMENTAL DATA
GRAPHITE
IONIC COMPOSITION
NEODYMIUM LASERS
PLASMA DIAGNOSTICS
PROTECTIVE COATINGS
SURFACE COATING
THIN FILMS