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The IITRI RF process laboratory and field results on oil shale and tar sands

Conference · · Energy Technol. (Wash., D.C.); (United States)
OSTI ID:5497570
The IITRI RF process for oil shale can be carried out at 350/sup 0/ to 375/sup 0/C instead of 500/sup 0/C, as normally used for other processes. This lower temperature makes the economics of the process even more favorable. Some investigations have measured low yields at 350/sup 0/C, which would not be cost effective. However, the authors have found that high yields are obtained if the shale is very slowly heated from 300/sup 0/ to 350/sup 0/ or 375/sup 0/C. This allows time for autogenously developed vapor to produce the liquid shale oil. In this way, the oil is not exposed for long periods to temperatures at which it can crack to light ends and char. Evidence for these effects was found in thermogravimetric analysis (TGA) experiments, which were two orders of magnitude faster than core pyrolysis experiments. This indicates that physical processes can limit the production rate for core experiments. The permeability as measured parallel to the bedding planes during pyrolysis of cores was 4400 millidarcies. The yield in core pyrolysis experiments ranged from 30 to over 100 percent of Fisher assay (depending on grade, temperature, and physical conditions) when the heating rate was 5/sup 0/C/min. When the core was heated from 300/sup 0/ to 350/sup 0/C at 10/sup 0/C/day the yield was 90 to 100 percent of Fisher assay. A field experiment on Utah tar sands heated a 60-ton volume of tar sand in situ to 200/sup 0/C. Eight barrels, or 24 percent of the bitumen in this volume was produced in 20 days. This extrapolates to 50 to 70 percent overall recovery in 6 months, which would allow production of upgraded oil below the world price.
OSTI ID:
5497570
Report Number(s):
CONF-820217-
Conference Information:
Journal Name: Energy Technol. (Wash., D.C.); (United States) Journal Volume: 9
Country of Publication:
United States
Language:
English