Potent solvents for C60 and their utility for the rapid acquisition of 13CNMR data for fullerenes. Technical report, No. 27
Technical Report
·
OSTI ID:5496372
Described are several solvents for the dissolution of fullerenes. The two best solvents found were 1,2-dichlorobenzene and 1-methylnaphthalene which dissolve C60 up to 24.6 and 33.2 mg/mL, respectively. The solubility data was obtained gravimetrically. Precipitates were obtained when C60 was treated with 1,3,5-trimethylbenzene or 1,2,4-trichlorobenzene. Scanning electron micrographs and thermogravimetric analysis data were obtained on the precipitates and compared to the data obtained for pure C60. The efficacy of 1,2-dichlorobenzene and 1-methylnaphthalene as 13C NMR solvents for fullerene analysis was demonstrated as well as the utility of 1,2-dichlorobenzene for the extraction of higher fullerenes from soot.
- Research Organization:
- South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry
- OSTI ID:
- 5496372
- Report Number(s):
- AD-A-273349/1/XAB; TR--27; CNN: N00014-89-J-3062
- Country of Publication:
- United States
- Language:
- English
Similar Records
Calorimetric studies of solvates of C{sub 60} and C{sub 70} with aromatic solvents
Organic photochemistry. 20. A method for estimating gas-phase rate constants for reactions of hydroxyl radicals with organic compounds from their relative rates of reaction with hydrogen peroxide under photolysis in 1,1,2-trichlorotrifluoroethane solution
Fullerene (C60) films for solid lubrication
Journal Article
·
Wed Feb 24 23:00:00 EST 1999
· Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical
·
OSTI ID:347555
Organic photochemistry. 20. A method for estimating gas-phase rate constants for reactions of hydroxyl radicals with organic compounds from their relative rates of reaction with hydrogen peroxide under photolysis in 1,1,2-trichlorotrifluoroethane solution
Journal Article
·
Wed Nov 30 23:00:00 EST 1988
· Environ. Sci. Technol.; (United States)
·
OSTI ID:6158426
Fullerene (C60) films for solid lubrication
Journal Article
·
Fri Oct 01 00:00:00 EDT 1993
· ASLE Transactions (American Society of Lubrication Engineers); (United States)
·
OSTI ID:5493331