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Title: The role of lignin and lignin-like materials during wood hydrolysis

Journal Article · · J. Eng. Appl. Sci.; (United States)
OSTI ID:5495409

The nature of the material precipitating from the acid prehydrolysates and hydrolysates of wood upon storage has been investigated. This material was analyzed for its sugar content, ultraviolet spectra, elemental composition, molecular weight distribution, and thermogravimetric behavior. All the results indicate that this material has the same properties as lignin. The results suggest also that this material is neither a resinification product from sugar decomposition nor extraneous materials of wood (resins, tannins, etc.). It is suggested, too, that the extraction of this material along with sugar during hydrolysis and prehydrolysis causes a considerable error in the results of wood analysis using standard methods based on weight loss. The actual percentages of lignin in the wood samples tested appear to vary from two to four times their values measured by standard methods. Consequently, the actual cellulose content of these materials may be far lower than has been reported. This has serious implications for schemes based on biomass conversion.

Research Organization:
National Research Centre, Dokki, Cairo, Egypt
OSTI ID:
5495409
Journal Information:
J. Eng. Appl. Sci.; (United States), Vol. 1:3
Country of Publication:
United States
Language:
English