New poly(carbosilane) models. 4. Derivatization of linear poly((methylchlorosilylene)methylene): Application to the synthesis of functional poly(carbosilanes) possessing a poly((methylsilylene)methylene) backbone

Journal Article · · Chemistry of Materials; (USA)

DOI:https://doi.org/10.1021/cm00014a028· OSTI ID:5492383

Bacque, E; Pillot, J -P; Birot, M; Dunogues, J; Lapouyade, P ^[1]; Bouillon, E; Pailler, R ^[2]

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1. Universite Bordeaux, Talence (France)
2. Laboratoire des Composits Thermostructuraux, Pessac (France)

To study the mechanisms of pyrolysis of poly(carbosilanes), as well as the effect of the structure of thee precursors upon properties of the resulting ceramics, novel organosilicon polymers with well-defined skeletons were prepared. Thus, linear poly(carbosilanes) formed of exactly alternate silicon atoms and methylene groups were synthesized. Owing to the presence of functional groups on silicon centers, cross-linking of these compounds was then investigated according to chemical routes, by creating disilane, disilazane, disiloxane, and hydrocarbon bridges between different poly(carbosilanic) sites. These polymers were characterized by physicochemical methods (IR, NMR, GPC, and TGA).

• OSTI ID: 5492383
• Journal Information: Chemistry of Materials; (USA), Journal Name: Chemistry of Materials; (USA) Vol. 3:2; ISSN CMATE; ISSN 0897-4756
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360201* -- Ceramics
Cermets
& Refractories-- Preparation & Fabrication
CERAMICS
CHEMICAL ANALYSIS
CHEMICAL PREPARATION
DATA
EXPERIMENTAL DATA
GRAVIMETRIC ANALYSIS
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
INFRARED SPECTRA
MAGNETIC RESONANCE
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC SILICON COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
RESONANCE
SILANES
SILICON COMPOUNDS
SPECTRA
SYNTHESIS
THERMAL ANALYSIS
THERMAL GRAVIMETRIC ANALYSIS