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Effect of smelter emissions on soil organic matter

Journal Article · · Bull. Ecol. Soc. Am.; (United States)
OSTI ID:5486631
Investigations into the effects of smelter emissions from the Sudbury, Ontario, mining area have revealed dramatic contamination of soils by both metals and sulfur dioxide. Concentrations of nickel and copper exceed 5000 ppm and 2000 ppm respectively within one mile of the smelter. Soil organic matter 31 miles from the smelter is typical of podzolic fulvic acid in both composition and structure. In contrast, soil organic matter from a site at one mile is extremely atypical. The total sulfur content is ten times that of the soil from 31 miles, but the sulfur content of the organic matter is 60 times higher than normal. It appears that in the organic matter from one mile, many of the carbon groups of fulvic acid have been replaced by sulfonic groups. In this way, the organic matter acts as an ion exchange resin with very strong metal chelating properties. This modified organic matter is extremely soluble and mobile in the environment.
Research Organization:
Univ. of Toronto, Ontario
OSTI ID:
5486631
Journal Information:
Bull. Ecol. Soc. Am.; (United States), Journal Name: Bull. Ecol. Soc. Am.; (United States) Vol. 55:2; ISSN BECLA
Country of Publication:
United States
Language:
English