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Single-electron-capture cross sections for 1--10-keV Li/sup +/ ions in alkaline-earth vapors

Journal Article · · Phys. Rev. A; (United States)
Total charge-neutralization cross sections have been measured with use of an attenuation method for Li/sup +/ ions in the energy range from 1 to 10 keV incident on thin targets of Mg, Ca, Sr, and Ba vapors. These cross sections exhibit an energy dependence characteristic of asymmetric charge exchange, increasing with collision energy up to a broad maximum, then decreasing at higher energies. The Li/sup +/+Ba cross section reaches a maximum value (sigma/sub m/) of 4.0 x 10/sup -14/ cm/sup 2/ at approx. 3.5 keV impact energy. The corresponding values of sigma/sub m/ for Sr and Ca are 2.85 x 10/sup -14/ cm/sup 2/ at 6.0 keV, and 3.3 x 10/sup -15/ cm/sup 2/ at 10 keV. The Li/sup +/+Mg cross section only attains a value of 1.1 x 10/sup -15/ cm/sup 2/ at the highest energy measured (10 keV), thus, sigma/sub m/ clearly occurs at even higher energies for this system. The energies at which these cross-section maxima occur increase monotonically through the series from Mg to Ba, while the magnitude of sigma/sub m/ decreases in that order. This ordering is consistent with the inverse ordering of the asymptotic energy defects for the process: Li/sup +/(1s/sup 2/)+M(ns/sup 2/)..-->..Li(2s) +M/sup +/(ns), where M is an alkaline-earth element.
Research Organization:
Chemical Physics Laboratory, SRI International, Menlo Park, California 94025
OSTI ID:
5481355
Journal Information:
Phys. Rev. A; (United States), Journal Name: Phys. Rev. A; (United States) Vol. 32:2; ISSN PLRAA
Country of Publication:
United States
Language:
English