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Low-energy e/sup -/-CO scattering in the static-exchange approximation

Journal Article · · Phys. Rev., A; (United States)
This paper presents a theoretical study of e/sup -/-CO scattering at collision energies from 1 to 7 eV in the static-exchange approximation. The T-matrix discrete-basis-set approach to electron-molecule scattering introduced by Rescigno, McCurdy, and McKoy is used together with the variational correction method of Fliflet and McKoy. The authors show the behavior of the /sup 2/..sigma.. and /sup 2/Pi channel eigenphases and extract the width and position of the /sup 2/Pi shape resonance. Comparison is made with other theoretical and semiempirical results and with the corresponding resonance parameters for e/sup -/-N/sub 2/ scattering. The momentum-transfer cross section is calculated and compared with the experimental data of Land and with other theoretical results.
Research Organization:
A. A. Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125
OSTI ID:
5481221
Journal Information:
Phys. Rev., A; (United States), Journal Name: Phys. Rev., A; (United States) Vol. 21:4; ISSN PLRAA
Country of Publication:
United States
Language:
English